电子自旋的概念在现代科技应用领域非常重要,其发现过程也充满戏剧性。本文从玻尔模型的困境出发,介绍了原子光谱的精细结构和反常塞曼效应、斯特恩–格拉赫实验、泡利不相容原理、乌伦贝克和古德斯密特的自旋假说、薛定谔–泡利方程,以及狄拉克方程等。即按照历史发展脉络,详细介绍了电子自旋理论发展历程中的实验和理论探索过程。最终,狄拉克方程将电子自旋及自旋–轨道耦合的贡献自然地包含,是现代电子理论的基本方程。最后,介绍了电子自旋在现代科技各方面的应用。The concept of electron spin is critically important in modern technological applications, and its discovery was full of drama. This article starts with the challenges faced by the Bohr model, introducing the fine structure of atomic spectra and the anomalous Zeeman effect, the Stern-Gerlach experiment, the Pauli exclusion principle, the spin hypothesis by Uhlenbeck and Goudsmit, the Schrödinger-Pauli equation, and the Dirac equation. Following the historical development, it outlines the experimental and theoretical explorations in the evolution of electron spin theory. Ultimately, the Dirac equation naturally includes the contributions of electron spin and spin-orbit coupling, serving as the fundamental equation of modern electron theory. Finally, the application of electron spin in various aspects of modern technology was introduced.
