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国家自然科学基金(51206100)

作品数:2 被引量:8H指数:2
相关作者:易维明付鹏安森萌更多>>
相关机构:山东理工大学更多>>
发文基金:国家自然科学基金山东省高等学校科技计划项目山东省自然科学基金更多>>
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Catalytic fast pyrolysis of corn stover in a fluidized bed heated by hot flue gas:Physicochemical properties of bio-oil and its application被引量:2
2017年
Fast pyrolysis of corn stover was performed at temperatures in the range of 450℃-525℃ in a fluidized bed.The chemical composition of the bio-oil acquired was analyzed by GC/MS,and its pH,kinetic viscosity and calorific values were determined.In the pyrolysis system used in this experiment,some improvements to former pyrolysis systems were done.Two screw feeders were used to prevent jamming the feeding system,and the condenser was equipped with some nozzles and a heat exchanger to cool quickly the cleaned hot gas into bio-oil.The results showed that the bio-oil yield increased with increasing pyrolysis temperature and then declined with a further increase in pyrolysis temperature.The highest bio-oil yield of 43.3 wt.%was obtained at 500℃ with the dolomite as bed material.The char yield always decreased with the increase of temperature.The major chemical compounds of bio-oil included acetol,butanone,acetic acid,propionic acid,ethylene glycol,phenol,etc.Pyrolysis oil was completely immiscible in diesel,but homogeneous emulsions were obtained when mixing the pyrolysis oil,emulsifier with diesel in different ratios.
Yang WenFu PengYi Weiming
关键词:BIO-OIL
基于纳米Ni/ZnO催化剂的乙酸蒸汽重整制氢研究
生物油蒸汽重整制氢技术被公认为是实现生物质大规模制取H2的最有应用前景的技术之一,开发利用潜力较高。基于国内外研究学者在生物油蒸汽重整技术理论基础研究和技术开发等方面已有的进展和问题,本文以Ni基纳米微粒催化剂为研究对象...
罗珊
关键词:乙酸催化剂
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乙酸水蒸气重整制氢反应的热力学分析被引量:6
2013年
以乙酸为研究对象,对乙酸水蒸气重整制氢进行热力学分析,通过热力学计算,考查温度、水碳比和压力等因素对反应平衡组成的影响。分析表明:与水碳比和压力对反应的影响相比,温度对反应的影响最为显著;反应平衡组分中H2和CO含量随温度的升高明显增大,但超过一定温度后H:含量开始下降;同时H2产率随水碳比的增大而逐渐增大,但增大趋势较为缓慢,CO和CH4的产率随水碳比增大而减小;受压力增大的影响反应平衡中各物质的量反而减小。在温度为400~650℃,水碳比为5:1,压力为常压时可获得较高可燃气产率和选择性。
安森萌付鹏易维明
关键词:热力学计算乙酸生物油
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