国家自然科学基金(20971032) 作品数:3 被引量:3 H指数:1 相关作者: 王路 周百斌 更多>> 相关机构: 哈尔滨工业大学 哈尔滨师范大学 更多>> 发文基金: 国家自然科学基金 黑龙江省博士后基金 黑龙江省自然科学基金 更多>> 相关领域: 理学 医药卫生 更多>>
One novel hybrid compound based on[AlW12O40]5- heteropolyanions and cobalt coordination polymer with in situ ligand:tetradentate N-heterocyclic ligand Under hydrothermal condition,one novel organic inorganic hybrid compound,[Co(Htpybenz)2][AlW12O40]H2O (1)(tpyb... Ying Chen文献传递 抗癌多金属氧酸盐 被引量:2 2013年 多金属氧酸盐具有独特的结构特征及优良的理化性能,已引起国内外科技工作者极大的兴趣与关注,特别是多金属氧酸盐作为抗癌化疗药物的研究,更成为本领域科学研究的前沿之一。本文综述了多金属氧酸盐作为抗癌生物活性药物的国内外研究进展,其内容主要包括多金属氧酸盐抗癌作用依据,同多、杂多金属氧酸盐不同结构类型的体外抗癌作用、体内抗癌作用及其抗癌作用机制等,提出了多金属氧酸盐抗癌研究应重点解决的几个问题,为进一步研究多金属氧酸盐抗癌药物活性提供了参考。 王路 周百斌 刘家仁关键词:多金属氧酸盐 抗癌 生物活性 化疗药物 The Two-electron reduced Basket-like[SrP6MoⅤ4MoⅥ14O73]8- Polyoxoanion Modified with {Ni(4,4’-bipy)(H2O)3} complex A new basket-like mixed-valent compounds [H2(4,4’-bipy )]5 {[Ni(4,4’-bipy)(H2O)3]2 [Ni(H2O)2]}[Sr(?)P6Mo2ⅤMo6Ⅵ... Kai Yu~(a文献传递 Syntheses,Crystal Structures and Electrochemical Properties of Two Molybdophosphates 被引量:1 2010年 Two molybdophosphate compounds,[Ni(bim)3]2[H2P2Mo5O23]·2H2O 1 and [Zn(bpy)2]2[Zn(bpy)(H2O)]2Zn[Mo6O12(OH)3(HPO4)4]2·9H2O 2 (bim = 2,2'-biimidazole,bpy = 2,2'-dipyridyl),have been synthesized under hydrothermal conditions and structurally characterized by elemental analysis,TG,and IR. The single-crystal X-ray analysis exhibits that 1 consists of one [H2P2Mo5O23]4-,two [Ni(bim)3]2+ cations and two lattice water molecules,while 2 is constructed from one sandwich-type [ZnP4Mo6] anion modified by four Zn-bpy complexes and nine lattice water molecules. The electrochemical behaviors of compounds 1 and 2 have been studied in detail based on solid bulk modified carbon paste electrodes of compound (CPEs). 于洋 于凯 周百斌 赵志凤 苏占华关键词:钼化合物 修饰碳糊电极 水热条件 X射线分析 Synthesis,structure and property of heteroatom-"embedded" X{P6Mo18O73} basket-like cluster cage modified with {Cu(2,2’-bpy)(H2O)} fragments A family of new organic-inorganic hybrid polyoxometalate based on basket-like mixed-valent polymolybdophosphat... Bin Wan文献传递 Polyoxometalates crystals synthesis and properties on catalytic preparation ethylene glycol The synthesis of new polyoxometalates(POMs) crystal is the main branch of chemistry[1].POMs,as environmently-f... Zhan-Hua Su~a文献传递 Ultrasonic synthesis of Cu2O nanostructures at room temperature and photoluminescent properties Shape-controlled synthesis of Cu2O nanostructures has been achieved in the ultrasonic method at room temperatu... Zeng-ming qin文献传递 含钴多酸对人肿瘤细胞抑制作用研究 <正>本文合成表征了药物配体咪唑修饰的含钴多酸(H2imi)2[Bi2W20O70Co2(H2O)6Na4(H2O)14]·2H3O·15H2O1,并研究其对人肿瘤细胞生长抑制活性。采用MTT法,细胞形态学分析,单细胞凝... 王路 张思琪 初丽丽 周百斌关键词:人肿瘤细胞 钴 文献传递 含黄胺配体多酸合成、晶体结构及体外抗肿瘤作用 <正>本文合成了含有磺胺配体的Keggin型多金属氧酸盐[{K(C6H10N2O2S)2(H2O)}2(SiW12O40)2]·2H3O+·10H2O(1),并通过元素分析、IR、TG、XPS、183WNMR和单晶X-射... 王路 张思琪 吴江 周百斌关键词:体外 磺胺 抗肿瘤 文献传递 Two-Dimensional layer paradodecatungstate by in aqueous solution synthesis:[{Cu0.5(H2O)}2{Cu0.5(H2O)2}2 {Cu(bim)(H2O)2}2(H4W12O42)]·10H2O A novel polyoxotungstate, [{Cuo5(H2O)}2{Cu0.5(H2O)2}2{Cu(bim)(H2O)2}2(H4W12O42)]·1 0H2O 1,(bim = 2,2’-biimidaz... Song Gao文献传递