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含氨基酸单元的手性主体的合成及手性识别研究被引量：9: 2006年; 以L-丙氨酸和2,7-二萘酚为原料通过简单的方法合成了二种带有荧光基团萘的手性阴离子主体(1和2),用红外光谱、质谱、元素分析、核磁共振氢谱及碳谱表征了它们的结构.用荧光光谱及核磁共振氢谱研究了主体与二苯甲酰酒石酸阴离子的相互作用,结果表明1,2与D-或L-二苯甲酰酒石酸阴离子均形成1∶1的配合物,主体1展现出良好的对二苯甲酰酒石酸阴离子对映选择性识别能力.; 徐括喜刘顺英何永炳秦海娟卿光焱胡翎; 关键词：荧光传感器手性识别氨基酸衍生物

Highly Selective Fluorescent Chemosensor for Dihydrogen Phosphate via Unique Excimer Formation in Water: ＜正＞A novel luminescent zinc coordination sensor 1 has been synthesized. Among various anions, introducing dihy...; HUANG Xiao-huan QING Guang-yan HE Yong-bing~* Department of Chemistry, Wuhan University, Wuhan (430072) PRC; 文献传递

Selective Recognition Properties of Two Fluorescence Receptors for Anions in Aqueous Solution: ＜正＞Three fluorescent receptors have been synthesized;their recognition properties to anions in aqueous solutio...; CHEN Zhi-hong HE Yong-bing~* Department of Chemistry, Wuhan University, Wuhan (430072); 关键词：RECOGNITION FLUORESCENCE; 文献传递

Enantioselective Fluorescent Sensor Based on Calyx[4]arene and S-Binol for the Recognition of N-Boc-glutamate: New chiral macrocyclic receptor 4 based on calix[4]arene and S-BINOL units was synthesized.The binding propert...; HU Chen-guang HUANG Xiao-huan CHEN Zhi-hong HE Yong-bing~* Department of Chemistry, Wuhan University, Wuhan (430072) P. R. China; 关键词：CALIXARENE; 文献传递

Chiral Recognition Property of a Ligand-metal Complex Receptor to Anions in Aqueous Solution: The chiral Fluorescent receptor 1-Cu has been synthesized, the recognition to chiral a anions has been studied...; CHEN Zhi-hong HE Yong-bing~* HU Chen-guang MENG Ling-zhi Department of Chemistry, Wuhan University, Wuhan (430072) PRC; 关键词：AQUEOUS; 文献传递

Synthesis and Enantioselective Discrimination of Chiral Fluorescence Receptors Bearing Amino Acid Units被引量：2: 2007年; Two chiral fluorescence receptors （1, 2） were synthesized, and their structures were characterized by IR, ^1H NMR, ^13C NMR, mass spectra and elemental analysis. The chiral recognition of receptors was studied by ^1H NMR and fluorescence spectra. The results demonstrate that receptors and dibenzoyl tartrate anion formed a 1 ： 1 complex. The receptor 1 exhibited a good enantioselective recognition ability toward the enantiomers of dibenzoyl tartrate anion.; 徐括喜何永炳卿光焱秦海娟刘顺英孟令芝; 关键词：SYNTHESIS FLUORESCENCE

基于杯[4]芳烃的手性识别被引量：6: 2008年; 手性杯芳烃是一类重要的主体化合物,在手性识别、对映体分离和不对称催化等方面有着广泛的用途。杯[4]芳烃因其稳定的构象和易于修饰的特点,成为研究最为广泛的杯芳烃分子,其中大量的文献报道了能够用于对映体识别和检测的手性杯[4]芳烃。在手性识别的研究中,荧光、紫外和核磁是3种最常见的研究方法,本文根据这3种方法进行分类,综述了近年来以杯[4]芳烃为分子骨架的手性受体的合成及其在手性识别中的应用。最后对手性杯[4]芳烃的发展前景作了展望。; 卿光焱刘顺英何永炳; 关键词：手性识别杯[4]芳烃

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国家自然科学基金(20572080)