＜正＞In the past decade,chemists have paid their attention to the design and construction of extended metal- org...
Zhi-Long Wang Guo-Yu Yang~* State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China.
＜正＞The search for microporous materials with new topologies has been extensively carried out owing to the wide...
Zhao Jun-Wei Yang Guo-Yu~* State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China
The ultrafast dynamics of benzaldehyde upon 260, 271, 284, and 287 nm excitations have been studied by femtosecond pinup-probe time-of-flight mass spectrometry. A bi-exponential decay component model was applied to fit the transient profiles of benzaldehyde ions and fragment ions. At the S2 origin, the first decay of the component was attributed to the internal conversion to the high vibrational levels of S1 state. Lifetimes of the first component decreased with increasing vibrational energy, due to the influence of high density of the vibrational levels. The second decay was assigned to the vibrational relaxation of the S1 whose lifetime was about 600 fs. Upon 287 nm excitation, the first decay became ultra-short （-56 fs） which was taken for the intersystem cross from S1 to T2, while the second decay component was attributed to the vibrational relaxation. The pump-probe transient of fragment was also studied with the different probe intensity at 284 nm pump.
Transition metal borate materials have attracted considerable attention due to their rich structural chemistry...
Rong Cheng Yang Guo-Yu~* State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China.
＜正＞During the past decade,the research in rapidly growing polyoxometalate（POM）area has focused on the design a...
Shou-Tian Zheng Guo-Yu Yang~* State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China.
Fragmentations of N2 in linearly polarized femtosecond 410 and 820 nm intense laser fields were studied by using the velocity mapping technique. Different behaviors of N2 at 410 and 820 nm were observed. Both the kinetic energy distributions and angular distributions of fragment ions in 410 nm field show weak dependency on laser intensities in the non- saturation regime, in contrast to the case in 820 nm. Different excited electronic states, i.e., non-Coulombic potentials populated via vertical＇excitation, are suggested to play crucial roles in fragmentations at short wavelength.
＜正＞At present,many examples of metal-organic frameworks（MOFs）have been reported for the default nets expected ...
Bing Li Guo-Yu Yang State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002 (China).
The reaction mechanism of 1-chloroethane with hydroxyl radical has been investigated by using density functional theory （DFT） B3LYP/6-31G （d, p） method. All bond dissociation enthalpies were computed at the same theoretical level. It was found that hydrogen abstraction pathway is the most favorable. There are two hydrogen abstraction pathways with activation barriers of 0.630 and 4.988 kJ/mol, respectively, while chlorine abstraction pathway was not found. It was observed that activation energies have a more reasonable correlation with the reaction enthalpy changes （ΔHr） than with bond dissociation enthalpies （BDE）.
＜正＞Borate compouds are of great interest due to their structure chemistry and important practical applications...
Gao-Juan Cao Guo-Yu Yang~* State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China
