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国家自然科学基金(40973090)

作品数:4 被引量:36H指数:3
相关作者:吴丰昌王静张润宇黎文郭建阳更多>>
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发文基金:国家自然科学基金国家重点基础研究发展计划中国科学院西部之光基金更多>>
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河流-湖泊系统中溶解有机质的示踪及迁移被引量:9
2012年
应用同步和三维荧光光谱对夏季贵州红枫湖、百花湖河流-湖泊系统的DOM(溶解有机质)进行识别和示踪,重点揭示了人为来源DOM的迁移和影响.结果表明,人为来源DOM比例较大的水体r(287 nm/332 nm)(同步荧光光谱指数)均大于1,r(B/C)(三维荧光光谱指数)较高,287 nm处的同步荧光峰是有机污染物的特征峰.与红枫湖表层水相比,百花湖表层水出现明显的类蛋白荧光峰,且r(287 nm/332 nm)(2.7)远大于红枫湖(0.7),指示百花湖中人为来源ρ(DOM)高于红枫湖.东门桥河向百花湖输送了较多人为来源DOM,但在百花湖水体纵向剖面4 m以下受到的影响较小.经过稀释和净化百花湖出口人为来源的ρ(DOM)已降至较低水平.同步荧光和三维荧光光谱联合可用来识别和示踪水体中人为来源ρ(DOM).
黎文吴丰昌王静郭建阳王立英白英臣张润宇
关键词:同步荧光光谱三维荧光光谱溶解有机质湖泊
Water quality criteria research and progress被引量:18
2012年
Water quality criteria (WQC) are threshold limits for pollutants or other hazard factors in the ambient water environment, which are based on scientific experiments and extrapolations. Until now, there is limited information available regarding the study of water quality criteria in China. It is imperative to launch national-level systematic WQC studies that focus on the regional characteristics of China and provide scientific support for the enactment or revision of water quality standards and environmental management. This article reviews the concept of WQC and discusses the methodology and global progress of WQC research. The article also summarizes the key scientific issues in WQC research, including species sensitivity distribution, toxicological endpoint selection, and models selection. Furthermore, we can adopt the derivation method used in the USA and divide WQC into acute and chronic criteria. Finally, considering the current status of WQC research in China, we point out important directions for future national studies, including the selection of native species and the comprehensive use of models.
FENG ChengLian WU FengChang ZHAO XiaoLi LI HuiXian CHANG Hong
关键词:BIOTA
Derivation of water quality criteria for representative water-body pollutants in China被引量:16
2012年
In this study, toxicological data for zinc (Zn), cadmium (Cd), hexavalent chromium (Cr (VI)), benzene, and nitrobenzene were collected from various databases and publications, screened and then constructed into species sensitivity distribution (SSD) curves. Then water quality criteria (WQC) were derived for protection of the freshwater aquatic life in China against five representative pollutants. The values derived in this study were compared with those issued by the US Environmental Protection Agency and the Chinese national environmental standard for surface water to identify factors underlying the differences. The results showed that the SSD curves for the five pollutants differed significantly, with the examined aquatic species being gen- erally more sensitive to Zn, Cd, and Cr (VI) than benzene and nitrobenzene. The acute WQC were: 48.43 μg L-1 for Zn, 0.4218 μg L-1 for Cd, 45.79μg L-1 for Cr (VI), 2651 μg L-1 for benzene, and 1426 μg L-1 for nitrobenzene. The chronic WQC were: 20.01μg L-1 for Zn, 0.2428 μg L-j for Cd, 14.22 μg L-1 for Cr (VI), 530.2 μg L J for benzene, and 286.2 μg L-1 for nitroben- zene. The results of this comparative study of representative pollutants may offer guideline values for future WQC studies for China.
WU FengChangFENG ChengLianZHANG RuiQingLI YuShuangDU DongYang
关键词:BIOTA
金属的理化性质和地壳丰度的相互关系初步研究
2015年
本文旨在探讨金属元素的理化性质和其地壳丰度(CA)的分布规律。利用相关性分析和集对分析研究了金属的理化性质和其地壳丰度的关系。结果表明,金属元素21种理化参数与地壳丰度之间均有不同程度的相关性。其中10种理化参数和地壳丰度显著相关(P≤0.05),包括共价指数(X2mr)、原子密度(ρ)、原子序数(AN)、原子量(AW)、有效核电荷(Z*)、电负性(Xm)、软指数(σp)、电子亲和能(EA)、极化力(Z*2/r)和电化学势(ΔE0)。集对分析进一步表明:X2mr,ρ,Z*和Xm与log(CA)之间趋同性较好,支持了相关分析的结论。研究结果暗示金属的理化性质与地壳丰度之间存在密切的内在关系,这为地球演化成因、元素丰度演变规律提供了新证据,对岩石、矿产资源开发和利用等有重要意义。
刘静穆云松王颖陈程朱元荣吴丰昌
关键词:环境地球化学定量结构活性相关集对分析
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