A very simple model based on the Quadrupole method was used in thetheoretical analysis of thermal diffusivity of composite materials of Cu-PVC, PVC-Cu-PVC, andCu-PVC-Cu. The use of MATLAB software with a return to real space using the Stehfest algorithm makesthe time of calculation very short. The thermal responses on the rear face of each consideredsample, which determine the thermal diffusivity were represented. A mathematical demonstration whichconfirmed the results was given. Thermal diffusivity determined from the rear face thermalresponses were compared with the results of the thermal diffusivity calculated by considering thecomposite materials to be homogeneous, and a discussion on the two kinds of results was provided.