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国家自然科学基金(29876022)

作品数:8 被引量:24H指数:3
相关作者:朱家骅夏素兰冯昭华关国强杨雪峰更多>>
相关机构:四川大学华盛顿大学更多>>
发文基金:国家自然科学基金国家教育部博士点基金更多>>
相关领域:化学工程理学更多>>

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气雾两相受限射流特性的研究被引量:7
2001年
本文采用自由射流理论研究了有限空间中气雾两相射流的流动特性 ,考虑雾相的存在对气相流速的作用 ,并由此推出了受限气雾两相流气速分布和雾相浓度分布计算方法 ,结果表明雾滴的卷入对气流的流动起到了阻滞作用 ,使其流速减小 ,在此基础上对受限射流在排出口附近存在的分离面进行了讨论 ,并采用单颗粒动力学模型求解了雾滴的速度分布 ,得知当雾滴的直径dp =5 μm ,在距喷嘴出口 30mm的地方将雾滴加入到出口气速u0 =140m/s的气相射流中时 ,雾滴在 15mm左右的距离内就能被加速到与气流等速 ,最后经过实验论证得知模型计算值与实验值吻合较好 ,该模型能较好的体现有限空间中的气雾两相射流特性。
雍炼夏素兰朱家骅
关键词:流速自由射流化学工程
Numerical Simulation of Single Microparticle Trajectory in an Electrodynamic Balance
2004年
By introducing Oseen's formula to describe the viscous drag force, a more complete motion equation for a charged microparticle levitated in an electrodynamic balance (EDB) has been put forward and solved numerically by the classic Runge-Kutta method in this paper. The theoretical results have firstly demonstrated the existence of the particle oscillations and their characteristics, especially of the springpoint oscillation at large amplitude .And through the comparisons of theoretical and experimental trajectories, the adopted motion equation has proved to be able to rigorously describe the particle motion in non-Stokes region--the shape of trajectory and frequencycharacteristics are fairlv consistent and the deviations of amnliturla c^n n^llzll^r ho lo~ th^n
冯昭华朱家骅杨雪峰夏素兰关国强Davis E.J.
关键词:EDB
EDB中微米单颗粒振荡特性
2004年
改进了Davis关于微米单颗粒在EDB(electrodynamicbalance)中悬浮的两区理论 ,通过引入Oseen曳力公式和非齐次项 ,建立了振荡条件下颗粒完整的运动微分方程 ,并对其运动轨迹进行了数值模拟 .从理论上证实了颗粒在EDB中存在稳定的阻尼振荡过渡区 ,给出了不同于Davis理论的三区状态图 (δ β图 ) ,从而构建了振荡条件下颗粒EDB研究的理论基础 .这些理论结果的可靠性通过实验也得到了很好的验证 .
冯昭华朱家骅杨雪峰夏素兰关国强Davis E.J
关键词:EDB振荡特性数值模拟
余热蒸汽循环载热的煤气甲烷化工艺被引量:6
2009年
对余热推动蒸汽循环载热煤气甲烷化节能工艺理论分析和计算表明,工艺气体载热能力正比于汽/气比H,通过蒸发/冷凝耦合的两相流传热传质可使H达3.0~4.0,使甲烷化反应绝热温升控制在300~400℃范围。该工艺节省了循环压缩机及其功耗,甲烷化工艺的能量效率提高6%以上。现场单管试验初步证明,高汽/气比不影响甲烷化催化剂反应活性。
沈倩陈建利夏素兰朱家骅
关键词:煤气甲烷化节能工艺蒸汽循环
Effect of Graft Yield on the Thermo-Responsive Permeability Through Porous Membranes with Plasma-Grafted Poly(N-isopropylacrylamide)Gates被引量:7
2003年
The effect of graft yield on both the thermo-responsive hydraulic permeability and the thermo-respousive diffusional permeability through porous membranes with plasma-grafted poly(N-isopropylacrylamide) (PNIPAM)gates was investigated. Both thermo-respousive flat membranes and core-shell microcapsule membranes with a wide range of graft yield of PNIPAM were prepared using a plasma-graft pore-filling polymerization method. The grafted PNIPAM was formed homogeneously throughout the entire thickness of both the fiat polyethylene membranes andthe microcapsule polyamide membranes. Both the hydraulic permeability and the diffusional permeability were heavily dependent on the PNIPAM graft yield. With increasing the graft yield, the hydraulic permeability (water flux) decreases rapidly at 25℃ because of the decrease of the pore size; however, the water flux at 40℃ increases firstly to a peak because of the increase of hydrophobicity of the pore surface, and then decreases and finally tends to zero because of the pore size becoming smaller and smaller. For the diffusional permeability, the temperature shows different effects on the diffusional permeability coefficients of solutes across the membranes. When the graft yield was low, the diffusional coefficient of solute across the membrane was higher at temperature above the lower critical solution temperature (LCST) than that below the LCST; however, when the graft yield was high, the diffusional coefficient was lower at temperature above the LCST than that below the LCST. It is very important to choose or design a proper graft yield of PNIPAM for obtaining a desired thermo-respousive 'on/off' hydraulic or ditfusional permeability.
褚良银朱家骅陈文梅NIITSUMA TakuyaYAMAGUCHI TakeoNAKAO Shin-ichi
关键词:聚(N-异丙基丙烯酰胺)
振动微液滴的传质机理与模型被引量:2
2004年
提出了微液滴振动传质的机理模型 ,基于微液滴振动引起的周围流体介质周期性变化流场和基本输运方程 ,得到简化的传质控制方程及其数值解 ,模拟结果表明传质组分的浓度分布具有明显的非均匀特征 ,其迎流面的浓度梯度显著大于背流面 ,导出的平均Sherwood数和传质速率随振动频率增加而增大 .采用电动力学天平中作一维拟简谐振动的十二烷醇微液滴在氮气介质中的蒸发传质实验数据对模型进行验证 ,结果表明本文模型所预测的平均Sherwood数变化趋势与实验结果一致 ,平均Sherwood数预测误差为 39 5 % 。
关国强朱家骅杨雪峰冯昭华余徽DAVIS E. James
关键词:振动传质
蒸汽喷射循环煤气甲烷化工艺研究被引量:1
2000年
提出无外加动力的蒸汽喷射自循环煤气甲烷化工艺。 2 5L、15 0h现场单管实验表明 ,在入口 2 2 / 1的高水气比和 2 0 0 0h-1空速条件下 ,化肥工业通用的甲烷化催化剂具有良好的反应活性 ,单程CO甲烷化率可达 90 %以上。
夏素兰王江平朱家骅周勇夏代宽
关键词:煤气甲烷化节能工艺
Velocity Slip and Interfacial Momentum Transfer in the Transient Section of Supersonic Gas-Droplet Two-Phase Flows被引量:1
2002年
Modelling and simulations are conducted on velocity slip and interfacial momentum transfer for super-sonic two-phase (gas-droplet) flow in the transient section inside and outside a Laval jet(L J). The initial velocity slipbetween gas and droplets causes an interfacial momentum transfer flux as high as (2.0-5.0) × 104 Pa. The relaxationtime corresponding to this transient process is in the range of 0.015-0.090 ms for the two-phase flow formed insidethe LJ and less than 0.5 ms outside the LJ. It demonstrates the unique performance of this system for application tofast chemical reactions using electrically active media with a lifetime in the order of 1 ms. Through the simulationsof the transient processes with initial Mach number Mg from 2.783 to 4.194 at different axial positions inside theLJ. it is found that Mg has the strongest effect on the process. The momentum flux increases as the Mach numberdecreases. Due to compression by the shock wave at the end of the L J, the flow pattern becomes two dimensionaland viscous outside the LJ. Laser Doppler velocimeter (LDV) measurements of droplet velocities outside the LJ arein reasonably good agreement with the results of the simulation.
魏文韫朱家骅夏素兰戴光清高旭东
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