Free radical fluoroalkylation of terminal alkenes and alkynes with iododifluoromethanesulfonamides has been successfully achieved.It was found that both the catalytic amount of sodium dithionite (Na2S2O4) and the stoichiometric amount of triethylborane (Et3B)/air can efficiently initiate the current free-radical atom transfer reaction.
ZHU JieMing,WANG Fei & HU JinBo CAS Key Laboratory of Organofluorine Chemistry
Difluoromethylene group(CF2) can act as an isopolar-isosteric substitute for oxygen,and replacement of the pho...
Zhang Feng,Fei Chen,and Xingang Zhang~* Key Laboratory of Organofluorine Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,345 Lingling Road,Shanghai 200032,China
＜正＞Sulfoximines（sometimes also called sulfoximides）are structurally unique derivatives of sulfones,which are a...
Jinbo Hu,Wei Zhang,Xiao Shen and Tao Luo Key Laboratory of Organofluorine Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,345 Ling-Ling Road,Shanghai 200032,China
＜正＞As an attractive alternative to traditional cross-coupling in construction of carbon-carbon（C-C） bonds, tra...
Shilu FanZhao Chenand Xingang Zhang~* Key Laboratory of Organofluorine ChemistryShanghai Institute of Organic ChemistryChinese Academy of Sciences345 Lingling RoadShanghai 200032China
