Lost foam casting(LFC)technology has been widely applied to cast iron and cast steel.However,the development of LFC for Al and Mg alloys was relatively slower than that for cast iron and cast steel.The application of LFC to Al and Mg alloys needs more effort,especially in China.In this paper,the development history of LFC is reviewed,and the application situations of LFC to Al and Mg alloys are mainly discussed.Meanwhile,the key problems of LFC for Al and Mg alloys are also pointed out.Finally,the prospects for LFC technology are discussed,and some special new LFC technologies are introduced for casting Al and Mg alloys.In future,the development trends of green LFC technology mainly focus on the special new LFC methods,metal material,coating,heat treatment,new foam materials as well as purification technology of tail gas,etc.
The microstructure evolution and mechanical properties of Mg-15Gd-3Y alloy were investigated in the as-cast and heat treated conditions. The microstrucmre evolution from as-cast to cast-T4 states involved a-Mg solid solution+Mg5(Gd,Y) phase→a-Mg supersaturated solid solution+rare earths compound Mg3(Gdl.26,Y0.74)→a-Mg supersaturated solid solution+rare earths compound Mg3(Gd0.Tas,Y1.255). It showed that 480 ℃/4 h was the optimal solution treatment parameter. If the solution temperature was high or the holding time was long, such as 520 ℃/16 h, an overheating phenomenon would be induced, which had a detrimental effect on the mechanical properties. When ageing at 225 and 200℃, the alloy would exhibit a significant age-hardening response and great long-time-age-hardening potential, respectively. The best mechanical properties were obtained at the parameters of 480 ℃/4 h+225 ℃/16 h, with the UTS of 257.0 MPa and elongation of 3.8%.
The influencing factors of surface alloying layer by evaporative pattern casting technology were investigated.A certain thickness alloying layer was formed on the surface of Mg-alloy matrix when the pouring temperature was 780°C with different vacuum degree and alloying powder size.The surface layer microstructure,micro area composition of the new phase formed on the matrix and the composition characteristics on the surface layer were examined by SEM and element scanning.The results show that the content of aluminum increases greatly on the surface layer.The micro-hardness of alloyed layer has a more obvious increase compared with that of the matrix.The size of alloying element and the vacuum degree are the key factors influencing the alloying layer,with the increase of element powder size from 0.074 to 0.15 mm and vacuum degree from 0.04 to 0.06 MPa,the surface alloying effect becomes better.
AZ91D surface alloying was investigated through evaporative pattern casting (EPC) technology. Aluminum powder (0.074 to 0.104 mm) was used as the alloying element in the experiment. An alloying coating with excellent properties was fabricated, which mainly consisted of adhesive, co-solvent, suspending agent and other ingredients according to desired proportion. Mg-alloy melt was poured under certain temperature and the degree of negative pressure. The microstructure of the surface layer was examined by means of scanning electron microscopy. It has been found that a large volume fraction of network new phases were formed on the Mg-alloy surface, the thickness of the alloying surface layer increased with the alloying coating increasing from 0.3 mm to 0.5 mm, and the microstructure became compact. Energy dispersive X-ray (EDX) analysis was used to determine the chemical composition of the new phases. It showed that the new phases mainly consist of/3-MglTAI12, in addition to a small quantity of inter-metallic compounds and oxides. A micro-hardness test and a corrosion experiment to simulate the effect of sea water were performed. The result indicated that the highest micro-hardness of the surface reaches three times that of the matrix. The corrosion rate of alloying samples declines to about a fifth of that of the as-cast AZ91D specimen.
Mechanical vibration was applied to the solidification of a lost foam cast(LFC) 356 aluminum alloy.Effects of mechanical vibration,with different peak acceleration,on the size and morphology of α-Al phase,and also on the mechanical properties of the castings were studied.Results indicated that α-Al dendrites gradually grow into equiaxed grains as the peak acceleration of vibration is increased.When the peak acceleration is between about 1 to 4 g,α-Al phase distribution is uniform and is refined obviously.α-Al dendrites are reduced and the mechanical properties of the castings are improved significantly when compared to those of the castings that are produced without vibration.However,when the peak acceleration is higher than 4 g,strong vibration will lead to defects formation,such as sand adhesion,while the amount and size of pores will be increased.And due to the turbulent flow that caused by strong vibration,the chance of forming large pores in the matrix has been increased significantly.The increase in defects will result in the deterioration of mechanical properties.
Zhao ZhongFan ZitianDong XuanpuTang BoPan DiLi Jiqiang