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国家自然科学基金(50575173)

作品数:8 被引量:31H指数:4
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8 条 记 录,以下是 1-8
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超低摩擦的理论与实践被引量:4
2008年
超低摩擦是纳米技术诞生后在摩擦学中近几年蓬勃发展的新领域。超低摩擦集成了量子力学、量子化学、纳米技术、分子动力学,为现代精密、低能耗、长寿命机械设计提供了强有力的摩擦学支撑。根据近几年超低摩擦的发展现状,分析了当前超低摩擦的理论及其局限性,阐明了当前产生超低摩擦的条件和材料特征,指出随着超低摩擦理论、技术和材料的大胆创新,超低摩擦必将在常规乃至恶劣工况下运行的装备上得到迅速应用。
董光能张宇军毛军红李健谢友柏
关键词:类金刚石膜分子动力学
Tribological behaviors of spot-textured TiN coatings on M2 high-speed steel under boundary lubricated conditions被引量:4
2007年
The effect of sliding duration on the tribological behaviors of spot patterned coatings was investigated. Two patterns based on physical vapor deposition (PVD) TiN coatings were used, such as, in-lined (IN) and staggered (ST) spots. The tribological behaviors were evaluated by using a Cameron-Plint wear test rig. The M2 steel discs deposited TiN coatings with IN and ST patterns slid against the ASSAB 17 tool steel pins at a speed of 0.23 m/s, in Shell Tellus T32 lubricant and were loaded with 900 N. The testing results on disc specimens with two types of PVD TiN spot patterns, all coated with a bias voltage of ?180 V and slid for 4, 8 and 11 h respectively, were presented. The results revealed that the in-lined coatings possessed relatively better wear behaviors than the staggered pattern coatings. Mechanisms for such superiority and for the cause of peeling were discussed. A relevant design approach was suggested for the application of such patterned coatings.
Guangneng DongMeng HuaJian LiHing-Yin MaYoubai Xie
关键词:织构边界润滑
Molecular dynamics simulation of the deposition process of hydrogenated diamond-like carbon (DLC) films被引量:2
2008年
The deposition process of hydrogenated diamond-like carbon (DLC) film greatly affects its frictional properties. In this study, CH3 radicals are selected as source species to deposit hydrogenated DLC films for molecular dynamics simulation. The growth and structural properties of hydrogenated DLC films are investigated and elucidated in detail. By comparison and statistical analysis, the authors find that the ratio of carbon to hydrogen in the films generally shows a monotonously increasing trend with the increase of impact energy. Carbon atoms are more reactive during deposition and more liable to bond with substrate atoms than hydrogen atoms. In addition, there exists a peak value of the number of hydrogen atoms deposited in hydrogenated DLC films. The trends of the variation are opposite on the two sides of this peak point, and it becomes stable when impact energy is greater than 80 eV. The average relative density also indicates a rising trend along with the increment of impact energy, while it does not reach the saturation value until impact energy comes to 50 eV. The hydrogen content in source species is a key factor to determine the hydrogen content in hydrogenated DLC films. When the hydrogen content in source species is high, the hydrogen content in hydrogenated DLC films is accordingly high.
ZHANG Yujun DONG GuangNeng MAO JunHong XIE YouBai
关键词:分子动力学DLC
含氢类金刚石膜沉积过程的分子动力学模拟被引量:8
2007年
含氢类金刚石膜(diamond-like carbon,DLC)的超低摩擦特性与其沉积制备过程密切相关.采用分子动力学模拟的方法,计算了以CH3基团为沉积物,在多种不同入射能下制备含氢DLC膜的动力学过程.通过沉积原子数统计分析、薄膜密度和sp杂化分析考察了含氢DLC膜的结构特性.通过比较模拟结果,发现随着入射轰击能量的增加,含氢类金刚石膜中碳的含量总体上呈现增加的趋势;在含氢DLC膜中所沉积的氢原子数存在峰值,峰值前后变化趋势相反,大于80eV以后趋于饱和与稳定,薄膜相对密度也随之增加,达到50eV时趋于稳定值;膜中碳原子比氢原子具有更强的成键能力,易与基底发生化学吸附;沉积源基团的氢含量决定生长成膜以后的薄膜氢含量,沉积源基团中的氢含量高,则所生长薄膜的氢含量高.
张宇军董光能毛军红谢友柏
关键词:分子动力学模拟入射能
类金刚石膜形态的分子动力学模拟研究被引量:10
2007年
类金刚石膜(Diamond-like carbon,DLC)优异的性能与碳原子sp2、sp3杂化密切相关。本文采用分子动力学方法,分别模拟计算了以C原子和CH3原子团为主要沉积物,在不同入射能量下制备无氢DLC膜和含氢DLC膜的动力学过程。研究了所生长成的两类DLC膜的具体形态及s-p杂化特性。揭示了无氢和含氢的两类DLC膜中sp2与sp3键的形成与连接结构形式,模拟结果表明:合适的入射能量可获得致密的DLC膜。在中等入射能量下,得到的sp3键含量的计算结果较好地符合实验结果,体现了理论计算与分析对实验制备的指导意义。
张宇军董光能毛军红曾群锋谢友柏
关键词:类金刚石膜分子动力学模拟
Wet and Dry Tribological Behaviors of Circular Islandic Protrusion Patterns on M2 Steel Discs under Spinning Condition被引量:1
2008年
Under spinning conditions, lubricant on islandic spot patterned M2 steel disc ex-periences centrifugal and tangential force components. Depending upon the relative position of the spots and the flow of lubricant, accumulation of lubricant in front of patterned islandic spots creates thrusting to mating part and subsequently reduces contact between the mating couple. Whilst wear debris is likely to be spun off the plateau of the spots to their neighbouring valleys so as to reduce wear. Hence, it gives favorable tribological characteristics. Aiming at verifying such mechanisms, studies were performed on M2 steel disc specimens slid with ASSAB 17 tool steel pin. The M2 steel disc specimens were respectively (i) machined with non-patterned (NP), (ii) etched to produce in-lined (INE) islandic patterns, and (iii) etched to produce staggered (STE) islandic spot patterns. Results indicated that the INE patterned discs gave most favorable wear characteristics, the NP of the worse characteristics whilst the STE ranged in the middle. However, the actual contact mechanism leads to the descending sequence of favorable friction behaviors nominally as: NP, INE and STE.
马庆贤董光能
关键词:M2钢
类金刚石膜生长特性的分子动力学模拟被引量:1
2007年
类金刚石膜(Diamond-like Carbon,DLC)的沉积过程直接影响着薄膜分子结构,从而决定着最终薄膜的物理化学特性。采用分子动力学模拟的方法,计算了以C原子为沉积物,在50eV和100eV入射能量下制备无氢DLC膜的动力学过程,详细考察了不同生长阶段表面生成膜的生长特性。通过比较,模拟结果观察到并揭示出在一定的入射能量冲击下,基体表面薄膜的一种新的点—链—网成长过程及薄膜形成机制。同时发现,随着入射能量的增加,基底的逃逸原子数亦相应增加,基底原子向表面薄膜的扩散和渗透距离变长,薄膜密度在入射能量较高时,变化数量及趋势基本一致。
张宇军董光能毛军红曾群峰谢友柏
关键词:类金刚石膜分子动力学模拟
高速钢表面镀覆DLC膜的结构及其摩擦特性研究被引量:6
2007年
以高纯石墨作靶材、N2/Ar为工作气体,采用非平衡磁控溅射技术在高速钢上制备了光滑、致密、均匀的掺氮DLC膜。用XPS、Raman光谱仪表征了DLC膜的结构,并在球-盘摩擦试验机上研究了其摩擦特性。结果表明:工作气体中的N2比例对DLC膜结构及其摩擦特性影响较大,随着N2比例的增加薄膜中sp3的比例减少,而sp2和碳氮键的比例增加;随着N2比例的增加,薄膜摩擦因数先减后增,这与薄膜中sp3比例下降和sp2比例增加而导致薄膜的硬度以及内应力变化有关。就本试验而言,工作气体中N2比例不应高于20%。
曾群锋董光能谢友柏徐均琪杭凌侠
关键词:类金刚石膜非平衡磁控溅射
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