Hollow Al2O3 nanospheres with well-defined structure and shape were successfully prepared via flame spray pyrolysis (FSP) in the presence of a surfactant as droplet stabilizer. The morphology and structure of the nanospheres were systematically characterized by transmission electron microscopy, scanning electron microscopy, and N 2 sorption. A solution of hydrated aluminum nitrate, polyethylene glycol (PEG) and absolute ethanol was sprayed into a flame to transform droplets into particles after evaporation and surface nucleation, forming hollow Al2O3 nanospheres from aluminum nitrate decomposition. The surfactant was found effective in producing smaller droplets because of decreased surface tension and viscosity, while the combination of oxygen atoms on PEG chains and aluminum ions in solution reduced interfacial turbulence, leading to increased stability of the droplets.
For better performance of dye sensitized solar cells(DSSCs) ,a bilayer structured electrode was constructed by employing a mesoporous anatase TiO2 overlayer above a commercial P25 TiO2 nanoparticles underlayer. The mesoporous anatase TiO2,prepared through a facile surfactant-assisted sol-gel process,possessed large pore size and well inter-connected network structure,both beneficial for dye adsorption and electron transfer. The dye adsorption capability of the mesoporous TiO2 was nearly twice that of the P25 counterpart. In the electrode,the mesoporous TiO2 film enhanced both dye adsorption and lightharvest,to increase photocurrent(Jsc) from 12.32 to 14.78 mA/cm2. Compared to the single P25 TiO2 film,the synergy of the mesoporous TiO2 and the P25 TiO2 nanoparticle films in the electrode resulted in a 24% improvement in light-to-electricity conversion efficiency(η) . This bilayered electrode provides an alternative approach for further developing a photovoltaic device with better cell performance.
Jun JiangJian ZhangFeng GuWei ShaoChunzhong LiMengkai Lu
