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Sharpless四唑合成中沉淀或中间物的结构和表征: 近年来，四唑及其5-取代的四唑衍生物日益受到广泛重视，尤其在配位化学方面，能作为桥联配体与金属配位形成一系列新的化合物;在药物化学方面，能代替羧基起稳定新陈代谢的作用;在摄影工业方面，能作为添加剂制成感光材料。最近，Sh...; 王立中; 关键词：四唑四唑衍生物感光材料中间体配位聚合物; 文献传递

二维纳米空洞方格:诺氟沙星锰(Ⅱ)配合物(英文)被引量：5: 2002年; The reactions of norfloxacin(H-Norf)with Mn (ClO 4 ) 2 ·6H 2 O and Mn (OH) 2 yield Mn (H-Norf)(ClO 4 ) 2 ·2H 2 O(1)and[Mn (Norf) 2 ·4H 2 O] n (2),respectively.1is monomeric while2has a novel 2D neutral square grid with an antibacterial drug as buildi ng block.Crystal data for1:triclinic,space groupP1(No.2),a=9.0939(3),b=9.4395(3),c=12.7182(3)*!,α=111.447(2),β=90.340(2),γ=112.357(1)°,V=926.34(5)*! 3 ,Z =1,ρ cacl =1.664g·cm -3 .Mo Kαradiation(λ=0.71073*!),T=293(2)K,μ=0.595mm -1 ,R 1 =0.0692,w R 2 =0.1482for 2320observed reflectio ns from 4390independent reflection s,GOF =0.940;Crystal data for2:Monoclinic,P2 1 /c,a=5.7530(12),b=21.865(4),c=13.343(3)*!,β=98.25(3)°,V=1661.1(6)*! 3 ,Z =2,ρ cacl =1.527g·cm -3 ,T=293(2)K,μ=0.477mm -1 ,R 1 =0.0531,w R 2 =0.1552for2070observed reflections from 2870independent reflections,GOF =1.384.CCDC:140819;151063.; 王立中陈振锋王锡森李咏华熊仁根游效曾; 关键词：诺氟沙星抗生素配位化学

Sharpless四唑合成中捕获双四唑锌配合物(英文)被引量：8: 2002年; The reaction of malononitrile with Z nCl 2 and NaN 3 in the presence of 2,2’-bipyridine a nd water affords the first bis(tetrazole)Zn-complex intermediate,mono(2,2’-bipyridine)bis(tetrazolyl)methane aqua zinc*",[Zn(2,2’ -bpy)(BTZ)(H 2 O)]·(H 2 O) 2 (1)which gives a clue for Demko-Sharple ss’ tetrazole synthesis.Crystal data for1:C 13 H 18 N 10 O 4 Zn,M r =443.74,monoclinic,space group P2 1 /c,a=12.5705(18),b=16.078(2),c=9.1921(13)*!,β=95.010(3)°,V=1850.7(5)*! 3 ,Z =4.CCDC:197788.; 王立中王锡森李咏华白志平熊仁根熊明李国武; 关键词：水热合成锌配位聚合物

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